The reaction of S(3P) atoms with nitric oxide
作者:
A. Van Roodselaar,
K. Obi,
O. P. Strausz,
期刊:
International Journal of Chemical Kinetics
(WILEY Available online 1978)
卷期:
Volume 10,
issue 1
页码: 31-39
ISSN:0538-8066
年代: 1978
DOI:10.1002/kin.550100104
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractThe flash photolysis–vacuum ultraviolet kinetic absorption spectroscopy technique has been used to measure the absolute rate constant for the reaction of ground state S(3P) atoms withnitric oxide,\documentclass{article}\pagestyle{empty}\begin{document}${\rm S}\left({^{\rm 3} P} \right) + {\rm NO}\mathop {\longrightarrow}\limits^{\rm M} {\rm SNO}\left({{\rm M} = {\rm CO}_2} \right)$\end{document}as a function of nitric oxide concentration and total pressure. The rateconstant was determined to be 1.9±0.1 × 101112/mol2.sec at 298°K, with a high‐pressure limit of 9.3 ± 2.1×109l/mol·sec−1. The observed kinetics are consistent with a termolecular energy transfe
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