We study the reliability estimates of the non-standard mixture of degenerate (degenerated at zero) and exponential distributions. The Uniformly Minimum Variance Unbiased Estimator (UMVUE) and Bayes estimator of the reliability for some selective prior when the mixing proportion is known and unknown are derived. The Bayes risk is computed for each Bayes estimator of the reliability. A simulated study is carried out to assess the performance of the estimators alongwith the true and Maximum Likelihood Estimate (MLE) of the reliability. An example from Vannman (1991) is also discussed at the end of the paper.