Biphasic blends (mixtures) of liquid crystal ionomers (prepared from ferrocene containing liquid crystal polymers by a redox reaction) and partially sulfonated polystyrene combine the constituent properties in a way, which is dependent on the measuring method. Polarizing microscopy shows homogenous textures similar to the pure liquid crystal polymer. Mechanical measurements show however the elastomeric behaviour of sulfonated polystyrene. The phase separated structure of these blends is proved by differential scanning calorimetry measurements.