Study of an external spherical reference system for N.M.R. spectroscopy
作者:
D.J. Frost,
G.E. Hall,
期刊:
Molecular Physics
(Taylor Available online 1966)
卷期:
Volume 10,
issue 2
页码: 191-200
ISSN:0026-8976
年代: 1966
DOI:10.1080/00268976600100241
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
More accurate equations than previously used to describe a non-perfect spherical reference system are given, and experiments to confirm them described. When such a system is used to measure chemical shifts, there should be a correction due to the magnetic susceptibility of the material from which the sphere is made, as well as corrections due to the susceptibilities of the solutions. It is also shown that the change in magnetic field strength, caused by insertion of a sample into the pole gap of a magnet, may be significant in certain circumstances. The ‘substitution’ method of external referencing must therefore be used with care.
点击下载:
PDF (471KB)
返 回