Thermoactivated spectroscopy of heterovalent impurity traps in CdWO4
作者:
V. Tⱥle,
I. Tⱥleand,
L.L. Nagornaya,
期刊:
Radiation Effects and Defects in Solids
(Taylor Available online 1995)
卷期:
Volume 134,
issue 1-4
页码: 477-480
ISSN:1042-0150
年代: 1995
DOI:10.1080/10420159508227272
出版商: Taylor & Francis Group
关键词: CdWO4;impurities;defects;electron traps;TSL;luminescence
数据来源: Taylor
摘要:
Recombination luminescence emission spectra, TSL and trap spectra estimated by fractional glow technique (FGT), in nominally pure and Li-, Bi- and Ho-doped CdWO4, crystals are reported. According to the investigations by FGT heterovalent impurities Li, Bi and Ho causes localized electronic states which act as traps for charge carriers. It is shown that TSL results in emission of known blue-green luminescence band by emptying of the Li+-related traps in CdWO4-Li and yellow luminescence band by emptying of the Bi3+-related traps in CdWO4-Bi. It is proposed that blue-green and yellow luminescence occur by recombination correspondingly of free holes and free electrons at different intrinsic tungstate group related luminescence centers.
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