Determination of Thallium in Soil
作者:
K.S. Patel,
N. Agarwal,
期刊:
International Journal of Environmental Analytical Chemistry
(Taylor Available online 1992)
卷期:
Volume 46,
issue 1-3
页码: 63-70
ISSN:0306-7319
年代: 1992
DOI:10.1080/03067319208026997
出版商: Taylor & Francis Group
关键词: Spectrophotometry;extraction;thallium(III);soils
数据来源: Taylor
摘要:
A new spectrophotometric method is described for the determination of thallium in soil by extraction of Tl(III) with a toluene solution of N,N′-diphenylbenzamidine after acidification with 0.2–4.0 M HCl, and reaction of the extract with Crystal violet in the presence of 0.01–0.8 M HCl. The value of molar absorptivity of Tl(III)-X-CV complex (where X = Cl or Br; CV = Crystal violet) in toluene is 7.00 × 1041 mole−1cm−1at the absorption maximum of 610 nm. The detection limit of the method is 20 ng ml−1. The present method is free from interference of almost metal ions commonly associated with Tl. The method has been applied for analysis of the metal to soils.
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