The kinetics of anodic oxide growth
作者:
S.P. Grinberg,
Yoram Shapira,
Z. Calahorra,
期刊:
Philosophical Magazine Letters
(Taylor Available online 1987)
卷期:
Volume 55,
issue 6
页码: 305-310
ISSN:0950-0839
年代: 1987
DOI:10.1080/09500838708214702
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The process of anodic oxide growth has been investigated. It is shown that the obtained experimental results confirm the Fehlner-Mott oxidation model in the case of InSb, a typical compound of the 111-V group. We also present a kinetic theory of the anion migration in the formed oxide. The theory is based on the following assumptions.(a)The only species which moves through the formed oxide is the OH−anion.(b)The chemical reactions of OH−with In3+and Sb3+cations take place simultaneously and independently, in a thin layer of the oxide/InSb interface. The resulting solution of the kinetic equations describes the anion distribution in the formed oxide. A simple expression for the rate of oxidation is obtained. Another possible application of the presented theory is suggested.
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