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The kinetics of anodic oxide growth

 

作者: S.P. Grinberg,   Yoram Shapira,   Z. Calahorra,  

 

期刊: Philosophical Magazine Letters  (Taylor Available online 1987)
卷期: Volume 55, issue 6  

页码: 305-310

 

ISSN:0950-0839

 

年代: 1987

 

DOI:10.1080/09500838708214702

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The process of anodic oxide growth has been investigated. It is shown that the obtained experimental results confirm the Fehlner-Mott oxidation model in the case of InSb, a typical compound of the 111-V group. We also present a kinetic theory of the anion migration in the formed oxide. The theory is based on the following assumptions.(a)The only species which moves through the formed oxide is the OH−anion.(b)The chemical reactions of OH−with In3+and Sb3+cations take place simultaneously and independently, in a thin layer of the oxide/InSb interface. The resulting solution of the kinetic equations describes the anion distribution in the formed oxide. A simple expression for the rate of oxidation is obtained. Another possible application of the presented theory is suggested.

 

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