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The Thermal Decomposition of Polydichlorophosphazene

 

作者: J.R. Maccallum,   A.R. S. Werninck,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  （Taylor Available online 1971）
卷期: Volume 5, issue 3  

页码: 653-660

 

ISSN:0022-233X

 

年代: 1971

 

DOI:10.1080/00222337108061050

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The thermal decomposition of polydichlorophosphazene has been examined. The decomposition was found to be first-order with an activation energy of 22.5 ± 2 kcal mole−1. The products comprised a wide range of cyclic and linear dichlorophosphazenes. It is suggested that the decomposition reaction is initiated at the ends of the macromolecules.

 

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