Grafting of Vinyl Acetate-Methyl Acrylate Mixture Onto Cellulose. Effect of Monomer Concentration and Feed Composition
作者:
M. J. Fernandez,
I. Casinos,
G. M. Guzman,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1990)
卷期:
Volume 27,
issue 7
页码: 969-985
ISSN:0022-233X
年代: 1990
DOI:10.1080/10601329008544816
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The effects of monomer concentration and feed composition in the graft copolymerization of a mixture of vinyl acetate (VAc) and methyl acrylate (MA) onto cellulose, initiated by ceric ion, are studied. Two procedures for the reactants addition were employed and several grafting parameters were measured. MA is more reactive toward grafting than VAc, and the VAc-MA mixture shows an intermediate behavior. Minor amounts of MA favor VAc grafting, and minor amounts of VAc disfavor MA grafting. VAc is oxidated more easily by ceric ion than is MA. An explanation of the results is presented.
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