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Grafting of Vinyl Acetate-Methyl Acrylate Mixture Onto Cellulose. Effect of Monomer Concentration and Feed Composition

 

作者: M. J. Fernandez,   I. Casinos,   G. M. Guzman,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1990)
卷期: Volume 27, issue 7  

页码: 969-985

 

ISSN:0022-233X

 

年代: 1990

 

DOI:10.1080/10601329008544816

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The effects of monomer concentration and feed composition in the graft copolymerization of a mixture of vinyl acetate (VAc) and methyl acrylate (MA) onto cellulose, initiated by ceric ion, are studied. Two procedures for the reactants addition were employed and several grafting parameters were measured. MA is more reactive toward grafting than VAc, and the VAc-MA mixture shows an intermediate behavior. Minor amounts of MA favor VAc grafting, and minor amounts of VAc disfavor MA grafting. VAc is oxidated more easily by ceric ion than is MA. An explanation of the results is presented.

 

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