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Processing and properties of nanocrystalline Pb(Sc0.5Ta0.5)O3, Pb(Sc0.5nb0.5)O3and Pb(Mg1/3Nb2/3)O3films produced by RF-sputtering from ceramic targets

 

作者: Carlos Ziebert,   Andris Sternberg,   Heinz Schmitt,   Karl-Heinz Ehses,   JanK. Krüger,  

 

期刊: Integrated Ferroelectrics  (Taylor Available online 2000)
卷期: Volume 31, issue 1-4  

页码: 183-193

 

ISSN:1058-4587

 

年代: 2000

 

DOI:10.1080/10584580008215652

 

出版商: Taylor & Francis Group

 

关键词: relaxor;nanocrystalline;diffuse phase transition;superlattice

 

数据来源: Taylor

 

摘要:

Nanocrystalline thin films of different relaxor materials, namely Pb(Sc0.5Ta0.5)O3(PST), Pb(Sc0.5Nb0.5)O3(PSN), Pb(Mg1/3Nb2/3)O3(PMN) have been produced by RF-sputtering to investigate whether it will affect their dielectric properties if their grain size is reduced to the dimensions known from their nanodomains. The XRD shows that the amorphous film crystallizes in pyrochlore structure at lower temperatures and short times. Annealing at higher temperatures and far longer time intervals leads to an increasing amount of perovskite phase with a grain size in the nanometer range. These results including dielectric measurements will be presented and discussed.

 

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