Characterization of zeolitic acidity I. The cracking of 2 mole % n‐Butane over a fixed zeolite bed
作者:
H. Rastelli,
B.M. Lok,
J. A. Duisman,
D.E. Earls,
J.T. Mullhaupt,
期刊:
The Canadian Journal of Chemical Engineering
(WILEY Available online 1982)
卷期:
Volume 60,
issue 1
页码: 44-49
ISSN:0008-4034
年代: 1982
DOI:10.1002/cjce.5450600109
出版商: Wiley Subscription Services, Inc., A Wiley Company
数据来源: WILEY
摘要:
AbstractThe use of a two mole percent n‐butane in helium stream in a fixed bed mini‐reactor at a temperature of 500°C over a zeolite bed (20 to 40 mesh and ≤ 5 grams in weight) was found to be a good tool for characterizing zeolitic acidity. In a broad spectrum of various kinds of zeolites tested, the test results are especially useful in differentiating the extremely active materials from the very active ones. Among the zeolites tested, the decreases in the order of HΩ>H‐Zeolon>NH4‐ZSM‐5>NH4Y (thermally modified)>NH4‐erionite (thermally modified)>>HKL>NH4Y>NaY ˜ amorphous silica‐alumina. The calculated first order rate constant covered a range from over 10
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