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Mechanical denaturation of high polymers in solutions. XXXVI. Flow-induced crystallization of Bombyx Mori L. silk fibroin from the aqueous solution under a steady-state flow

 

作者: K. Yamaura,   Y. Okumura,   S. Matsuzawa,  

 

期刊: Journal of Macromolecular Science, Part B  (Taylor Available online 1982)
卷期: Volume 21, issue 1  

页码: 49-69

 

ISSN:0022-2348

 

年代: 1982

 

DOI:10.1080/00222348208205085

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The crystallization ofBombyx mori L.silk fibroin was carried out from a regenerated solution maintained in contact with air under a steady-state flow. The nucleation occurs at first close to the solution surface after a few seconds of stirring and then a fibrillar crystal propagates. The nucleation was considered to occur by the flow-induced, one-dimensional orientation of silk fibroin molecules which were adsorbed to the solution surface. The yield of precipitate after stirring for 2 hr was influenced by the temperature and concentration at low shear rate (below 200 sec−1), while it was not influenced at high shear rate (1000 sec−1), and was above 80%. Electron microscopy, X-ray diffraction, and DSC thermograms show that the precipitates consist of fine fibers of about 0.2 μm diameter and crystals which have the β-structure and a low orientation.

 

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