Preliminary communication : Development of an incremental system for the prediction of the nematic-isotropic phase transition temperature of liquid crystals with two aromatic rings
作者:
THIES THIEMANN,
VOLKMAR VILL,
期刊:
Liquid Crystals
(Taylor Available online 1997)
卷期:
Volume 22,
issue 4
页码: 519-523
ISSN:0267-8292
年代: 1997
DOI:10.1080/026782997209252
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
It is possible to express the transition temperature nematic-isotropic (TNI) for nematogens with just two aromatic ring systems as the sum of incremental values of substructural elements, denoted as substituents and bridging moieties. Of the 1426 mesogens that can be constructed by the elements for which the increments have been given, the TNI values of most can be predicted to within 10 C, the only notable exception being the 1,2-diphenylethenes.
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