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Analysis ofCu(In,&hthinsp;Ga)Se2solar cells: Why performance decreases with increasing Ga content

 

作者: J. E. Phillips,   W. N. Shafarman,  

 

期刊: AIP Conference Proceedings  (AIP Available online 1999)
卷期: Volume 462, issue 1  

页码: 120-125

 

ISSN:0094-243X

 

年代: 1999

 

DOI:10.1063/1.57959

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Solar cells have been made from uniformCu(In,&hthinsp;Ga)Se2films deposited by elemental evaporation with two different Ga compositions,Ga/[In+Ga]=0.30and 0.65. The solar cells fabricated from these uniform films have 15&percent; efficiency forGa/[In+Ga]=0.30,but the device efficiency is less than expected for the high Ga content due primarily to a decrease in fill factor and open circuit voltage. Analysis of current-voltage results have shown that the main cause of this decrease is a voltage dependent light generated current,JL,(V).Devices were fabricated with both standard (1 &mgr;m) and semi-transparent (0.04 &mgr;m) Mo contacts. Bi-facial spectral response measurements were made and analyzed on the devices with the semi-transparent Mo contacts in order to determine the changes in collection efficiency as a function of changing Ga composition and applied voltage. This analysis determined that the decrease in the light generated current with increasing voltage is primarily due to a reduction in minority carrier diffusion length, L, from about 0.8 to 0.1 &mgr;m. ©1999 American Institute of Physics.

 

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