Conformation Dependence of Electronic Structures in Polysilanes
作者:
Hiroaki Tachibana,
Yasujiro Kawabata,
Yutaka Moritomo,
Shin-Ya Koshihara,
Yoshinori Tokura,
RobertD. Miller,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1992)
卷期:
Volume 217,
issue 1
页码: 65-70
ISSN:1058-725X
年代: 1992
DOI:10.1080/10587259208046878
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Optical spectra (ordinary absorption, photoluminescence, electro‐absorption, and two‐photon absorption spectra) have been investigated for thin films of polysilanes with a variety of backbone conformations such as trans planar, alternating trans-gauche, helical, and disordered forms. The results observed have revealed new features of one‐dimensional exciton states characteristic of each conformation of the polymer backbone.
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