Extraction of some mineral acids by high molecular weight quaternary ammonium chloride
作者:
Taichi Sato,
Hiroshi Watanabe,
Shoji Kikuchi,
期刊:
Journal of Applied Chemistry and Biotechnology
(WILEY Available online 1975)
卷期:
Volume 25,
issue 1
页码: 63-72
ISSN:0375-9210
年代: 1975
DOI:10.1002/jctb.5020250107
出版商: John Wiley&Sons, Ltd
数据来源: WILEY
摘要:
AbstractThe distribution equilibria of hydrochloric, nitric, perchloric, sulphuric and phosphoric acids between aqueous solutions and a solution of tricaprylmethyl‐ammonium chloride in organic solvent have been investigated. The organic phases have been studied by infra‐red and nuclear magnetic resonance spectroscopy. As a result, it is found that at low aqueous acidity the extraction of these acids is governed by the ion exchange reaction, forming the mono‐quaternary ammonium salts of monobasic acids and the mono‐, di‐ (and tri‐) quaternary ammonium salts of di‐ (and tri‐) basic acids, and at higher acidity by the formation of the adducts to quaternary ammonium salts with a
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