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Thermodynamics of Polymer Solutions

 

作者: Robert F. Blanks,  

 

期刊: Polymer-Plastics Technology and Engineering  (Taylor Available online 1977)
卷期: Volume 8, issue 1  

页码: 13-33

 

ISSN:0360-2559

 

年代: 1977

 

DOI:10.1080/03602557708545030

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The widely used Flory-Huggins theory of polymer solution thermodynamics was presented in the literature in 1942 [1, 2]. It is based upon the quasilattice theory of solutions [3], and leads to an equation for the free energy of mixing polymeric solute with monomeric solvent which contains a combinatorial entropy of mixing term and a regular solution theory enthalpy of mixing term. In its original form the theory contains only one adjustable parameter, characteristic of the intermolecular forces between molecules in solution. Hildebrand's solubility parameter concept [4] may be used to estimate the value of this parameter.

 

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