A Self-Bracketing Search Technique for the Classical Dispersion Analysis of Infrared Reflectance Data
作者:
L.R. Brantley,
G. Andermann,
P. Sakamoto,
期刊:
Spectroscopy Letters
(Taylor Available online 1971)
卷期:
Volume 4,
issue 3-4
页码: 47-56
ISSN:0038-7010
年代: 1971
DOI:10.1080/00387017108064615
出版商: Taylor & Francis Group
关键词: dispersion analysis;infrared;reflectance data
数据来源: Taylor
摘要:
If an observed infrared reflectance band corresponds to a harmonic vibrational mode, then it is feasible by means of well known dispersion relationships to calculate reflectance values Rcfor an ideal reflectance curve that agrees with the curve obtained from experimentally observed Rxvalues. The technique of comparing Rcwith Rxhas been denoted as “classical dispersion,” or CD analysis. In the obtaining of dispersion parameters, such as oscillator strength (Sj), damping constant (Yj), and resonant frequency (vj) through CD analysis of infrared reflectance data, a number of methods have been used.
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