The photogelation of rubber sols in the absence of accelerators
作者:
R. Buckingham,
G. V. Planer,
期刊:
Journal of the Society of Chemical Industry
(WILEY Available online 1946)
卷期:
Volume 65,
issue 1
页码: 6-8
ISSN:0368-4075
年代: 1946
DOI:10.1002/jctb.5000650102
出版商: John Wiley&Sons, Ltd
数据来源: WILEY
摘要:
AbstractOn irradiation of rubber sols with ultra‐violet light in the absence of oxygen, gelation takes place under certain conditions. The nature of thin reaction was studied by following its progress by means of viscosity measurements. Reaction curved determined for rubber sols in carbon tetrachloride, in the absence of accelerators, were found to be fundamentally, of the same type as those obtained in their presence. They differed, however, in showing a slight initial decrease in viscosity owing 10 degradation, probably due to traces of oxygen. The mechanism of the reaction and the possible structures of the reaction feature are discusse
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