Structural Order and Photoelectric Properties of Organic Thin Films
作者:
Norbert Karl,
Jörg Marktanner,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1998)
卷期:
Volume 315,
issue 1
页码: 163-168
ISSN:1058-725X
年代: 1998
DOI:10.1080/10587259808044326
出版商: Taylor & Francis Group
关键词: organic thin films;order;disorder;rocking width;electron mobility;PTCDA
数据来源: Taylor
摘要:
Photoactiveorganicthin films are attracting rapidly growing attention. Model investigations are aiming at establishing a new era of electronics, based on molecular materials – with the potential of miniaturization down to the molecular level (“molecular electronics”). As a fundamental difficulty, however, electric, photoelectric and optoelectronic properties of organic thin film samples are often found to vary considerably with the preparation parameters. – Using vapor-deposited 3,4,9,10-perylene-tetracaboxylic- dianhydride (PTCDA) thin films and measuring the electron time-of-flignt mobility we prove that, what appears as poor reproducibility, largely is a consequence of a wide scatter of structural parameters, such as the degree of cystallinity and orientational order. We find that the electron mobility – over orders of magnitude – is (anti-)correlated with the width of the X-ray rocking curve of the respective sample, reaching 3×10-2cm2/Vs for our presently best one.
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