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Dynamic Viscosity and Excess Volume of the Ternary Heptane+Methylcyclohexane+1-Methylnaphtalene Versus Composition and Temperature

 

作者: P. Dauge,   C. Boned,   A. Baylaucq,   J. Jose,  

 

期刊: Physics and Chemistry of Liquids  (Taylor Available online 1998)
卷期: Volume 36, issue 3  

页码: 163-177

 

ISSN:0031-9104

 

年代: 1998

 

DOI:10.1080/00319109808030607

 

出版商: Taylor & Francis Group

 

关键词: Viscosity;excess energy of activation for viscous flow;ternary mixtures;hydrocarbons

 

数据来源: Taylor

 

摘要:

The density ρ and the dynamic viscosity η of the ternary mixture heptane+methylcyclohexane+1-methylnaphtaiene were measured at 303.15, 323.15 and 343.15K at atmospheric pressure for molar fractionsxi=0, 0.125, 0.25, 0.375, 0.5, 0.625, 0.75, 0.875 and 1 (with Σi=13xi= 1). The experimental data for η and ρ (135 values) can be used to evaluate the excess volumeVEand the excess energy of activation for viscous flow ΔGE. The density is modelled over the entire experimental domain of composition and temperature with an absolute average deviation of 0.03% and the dynamic viscosity with an absolute average deviation of 0.7%.

 

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