Homoisoflavanone. IV.Neue Inhaltsstoffe der Eucomin‐Reihe vonEucomis bicolor
作者:
Werner Heller,
Paul Andermatt,
Werner A. Schaad,
Christoph Tamm,
期刊:
Helvetica Chimica Acta
(WILEY Available online 1976)
卷期:
Volume 59,
issue 6
页码: 2048-2058
ISSN:0018-019X
年代: 1976
DOI:10.1002/hlca.19760590618
出版商: WILEY‐VCH Verlag GmbH
数据来源: WILEY
摘要:
Homoisoflavanones. IV. New constituents of the Eucomin Series ofEucomis bicolor.Four new homoisoflavanones, (E)‐7‐O‐methyl‐eucomin (2a), (—)‐7‐O‐methyleucomol (5), (+)‐3,9‐dihydro‐eucomin (7a) and 7‐O‐methyl‐3,9‐dihydro‐eucomin (8), were isolated from the bulbs ofEucomis bicolorBak. (Liliaceae). Their structures were determined by spectral data and synthesis. These compounds occur exclusively in the waxy material between the bulb leaves. Furthermore it was shown that only (Z)‐eucomin (1b) is genuine, (E)‐eucomin (1a) being an artefact. It is likely that2ais also not genuine. A new method for a sel
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