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Homoisoflavanone. IV.Neue Inhaltsstoffe der Eucomin‐Reihe vonEucomis bicolor

 

作者: Werner Heller,   Paul Andermatt,   Werner A. Schaad,   Christoph Tamm,  

 

期刊: Helvetica Chimica Acta  (WILEY Available online 1976)
卷期: Volume 59, issue 6  

页码: 2048-2058

 

ISSN:0018-019X

 

年代: 1976

 

DOI:10.1002/hlca.19760590618

 

出版商: WILEY‐VCH Verlag GmbH

 

数据来源: WILEY

 

摘要:

Homoisoflavanones. IV. New constituents of the Eucomin Series ofEucomis bicolor.Four new homoisoflavanones, (E)‐7‐O‐methyl‐eucomin (2a), (—)‐7‐O‐methyleucomol (5), (+)‐3,9‐dihydro‐eucomin (7a) and 7‐O‐methyl‐3,9‐dihydro‐eucomin (8), were isolated from the bulbs ofEucomis bicolorBak. (Liliaceae). Their structures were determined by spectral data and synthesis. These compounds occur exclusively in the waxy material between the bulb leaves. Furthermore it was shown that only (Z)‐eucomin (1b) is genuine, (E)‐eucomin (1a) being an artefact. It is likely that2ais also not genuine. A new method for a sel

 

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