Bottom electrodes for integrated Pb(Zr, Ti)O3 films
作者:
Philip D. Hren,
S. H. Rou,
H. N. Al-Shareef,
M. S. Ameen,
O. Auciello,
A. I. Kingon,
期刊:
Integrated Ferroelectrics
(Taylor Available online 1992)
卷期:
Volume 2,
issue 1-4
页码: 311-325
ISSN:1058-4587
年代: 1992
DOI:10.1080/10584589208215751
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Lower electrodes for Pb(Zr, Ti)O3 (PZT) used in ferroelectric random access memories must have good electrical conductivity and must interact as little as possible with the PZT film. We have evaluated a number of bottom electrodes for use with PZT films deposited by ion beam sputter deposition These electrodes include Pt, Pt/Ti, RuO2, ReO3, and CoSi23N4, all on SiO2/Si; and TiN and Pt on MgO. Films were studied by XTEM, Auger depth profiling, X-ray microanalysis, and XRD. Important issues for platinum include: a) microstructure (porous for magnetron sputtered Pt); b) rapid lead diffusion through porous Pt; c) adhesion (improved by raising deposition temperature or by adding a titanium layer); and d) hillock formation (related to compressive stress in platinum). RuO2 has good conductivity and has no apparent interfacial layer with PZT. Each of the remaining substrates has drawbacks: CoSi2 forms a surface oxide; ReO3 has poor phase stability; TiN oxidizes and loses conductivity.
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