Reactions of Alkyl Halides in Fused Salt Media
作者:
R. A. Bailey,
S. F. Prest,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1971)
卷期:
Volume 49,
issue 1
页码: 1-6
ISSN:0008-4042
年代: 1971
DOI:10.1139/v71-001
出版商: NRC Research Press
数据来源: NRC
摘要:
Passage of C1to C5haloalkanes through SnCl2–KCl melts results in halide exchange reactions, alkene formation, and rearrangement (including cyclization) reactions of the organic molecules. Relative reactivities, product distributions and melt composition effects are consistent with a carbonium ion mechanism in which the melt functions as a halide ion acceptor. Some control of product distribution by choice of Lewis acid character of the melt seems possible.
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