首页   按字顺浏览 期刊浏览 卷期浏览 Numerical Studies of Methane Catalytic Combustion Inside a Monolith Honeycomb Reactor U...
Numerical Studies of Methane Catalytic Combustion Inside a Monolith Honeycomb Reactor Using Multi-Step Surface Reactions

 

作者: CHEN-PANG CHOU,   JYH-YUAN CHEN,   GREGH. EVANS,   WILLIAMS. WINTERS,  

 

期刊: Combustion Science and Technology  (Taylor Available online 2000)
卷期: Volume 150, issue 1-6  

页码: 27-57

 

ISSN:0010-2202

 

年代: 2000

 

DOI:10.1080/00102200008952116

 

出版商: Taylor & Francis Group

 

关键词: Catalyst Combustion;Surface Mechanism;Numerical Simulation

 

数据来源: Taylor

 

摘要:

The heterogeneous oxidation of methane-air mixture in a honeycomb catalytic reactor is investigated numerically in the present study. An improved multi-step surface reaction mechanism for methane oxidation on platinum is proposed so that surface ignition of lean methane-air mixtures is better modeled. First, this surface mechanism is used to determine the apparent activation energy of methane-air catalytic combustion. The predicted activation energies are found to agree well with the experimental data by Trimm and Lam (1980) and by Griffin and Pfefferle (1990). The chemical model indicates that, depending on the surface temperature, the surface reaction rate is dominated by either the oxygen desorption rate or by the methane adsorption rate.

 

点击下载:  PDF (767KB)



返 回