Numerical Studies of Methane Catalytic Combustion Inside a Monolith Honeycomb Reactor Using Multi-Step Surface Reactions
作者:
CHEN-PANG CHOU,
JYH-YUAN CHEN,
GREGH. EVANS,
WILLIAMS. WINTERS,
期刊:
Combustion Science and Technology
(Taylor Available online 2000)
卷期:
Volume 150,
issue 1-6
页码: 27-57
ISSN:0010-2202
年代: 2000
DOI:10.1080/00102200008952116
出版商: Taylor & Francis Group
关键词: Catalyst Combustion;Surface Mechanism;Numerical Simulation
数据来源: Taylor
摘要:
The heterogeneous oxidation of methane-air mixture in a honeycomb catalytic reactor is investigated numerically in the present study. An improved multi-step surface reaction mechanism for methane oxidation on platinum is proposed so that surface ignition of lean methane-air mixtures is better modeled. First, this surface mechanism is used to determine the apparent activation energy of methane-air catalytic combustion. The predicted activation energies are found to agree well with the experimental data by Trimm and Lam (1980) and by Griffin and Pfefferle (1990). The chemical model indicates that, depending on the surface temperature, the surface reaction rate is dominated by either the oxygen desorption rate or by the methane adsorption rate.
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