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Liquid Crystal Solvents as Reaction Media for the Claisen Rearrangement

 

作者: W.E. Bacon,   GlennH. Brown,  

 

期刊: Molecular Crystals  （Taylor Available online 1969）
卷期: Volume 6, issue 1  

页码: 155-159

 

ISSN:0369-1152

 

年代: 1969

 

DOI:10.1080/15421406908082956

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

In the couse of our investigations of liquid crystals as solvents, we wish to report some kinetic data for the Claisen rearrangement. The thermal rearrangement of allyl phenyl ethers (1) proceeds by an intramolecular path to give an ortho-dienone (II) which rapidly enolizes to 2-allylphenols (III).

 

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