Detailed geological mapping and drilling has shown that the contact between the Cambrian volcano‐sedimentary sequence at Rosebery and the Mt Read Volcanics is formed by a major thrust fault dipping east at 40° and having a displacement of at least 1.5 km. The sedimentary sequence is part of the Dundas Group, a Middle to Late Cambrian forearc‐like sequence which unconformably overlaps the volcanics south of Rosebery. The Rosebery Thrust Fault marks the eastern boundary of a zone of folding, faulting and disruption which affects the Dundas Group and the tectonically interfingered and underlying basaltic greywacke‐mudstone sequence of the Crimson Creek Formation. At least some of this deformation occurred prior to deposition of the Ordovician Limestone, as evidenced by marked angular discordances. The complex area can be interpreted as a Cambrian accretionary prism‐forearc‐arc sequence developed above an east‐dipping subduction zone.