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Synthesis of critically cross‐linked microgels by dispersion polymerization

 

作者: M. Antonietti,   W. Bremser,   T. Pakula,  

 

期刊: Acta Polymerica  (WILEY Available online 1995)
卷期: Volume 46, issue 1  

页码: 37-44

 

ISSN:0323-7648

 

年代: 1995

 

DOI:10.1002/actp.1995.010460104

 

出版商: Akademie Verlag GmbH

 

数据来源: WILEY

 

摘要:

AbstractMicrogels with cross‐link densities close to the critical value of gel transition are synthesized via polymerization in microemulsion stabilized with a polymeric surfactant. The resulting structures are characterized by static and dynamic light scattering, viscometry, small angle neutron scattering and dynamic‐mechanical shear experiments.The proximity of the gel point influences the different properties in a different way. Global properties such as particle shape are closely connected with the gel point whereas the local structure and relaxation show critical behavior even quite far from the gel po

 

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