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Bulk modulus and thermal expansivity of melt polymer composites: Statistical versus macro‐mechanics

 

作者: Robert Simha,   R. K. Jain,   S. C. Jain,  

 

期刊: Polymer Composites  (WILEY Available online 1984)
卷期: Volume 5, issue 1  

页码: 3-10

 

ISSN:0272-8397

 

年代: 1984

 

DOI:10.1002/pc.750050104

 

出版商: Society of Plastics Engineers, Inc.

 

数据来源: WILEY

 

摘要:

AbstractPhysical properties of composites as a function of filler content have been described in the past through models requiring the solution of macroscopic equations of motion for an elastic continuum or, on a more empirical level, by the assumption of various compositional averaging schemes. We discuss a model drawn from our molecular mixture theory. This allows us to avoid the formal problems attending concentrated suspensions and introduces molecular filler‐medium interaction parameters. Comparisons with experimental material and empirical equations involving bulk modulus and thermal expansivity will be given. The theory opens the possibility of determining interfacial strengths from appropriate mechanical and thermal measurements and of predicting one set from another set of dat

 

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