Bulk modulus and thermal expansivity of melt polymer composites: Statistical versus macro‐mechanics
作者:
Robert Simha,
R. K. Jain,
S. C. Jain,
期刊:
Polymer Composites
(WILEY Available online 1984)
卷期:
Volume 5,
issue 1
页码: 3-10
ISSN:0272-8397
年代: 1984
DOI:10.1002/pc.750050104
出版商: Society of Plastics Engineers, Inc.
数据来源: WILEY
摘要:
AbstractPhysical properties of composites as a function of filler content have been described in the past through models requiring the solution of macroscopic equations of motion for an elastic continuum or, on a more empirical level, by the assumption of various compositional averaging schemes. We discuss a model drawn from our molecular mixture theory. This allows us to avoid the formal problems attending concentrated suspensions and introduces molecular filler‐medium interaction parameters. Comparisons with experimental material and empirical equations involving bulk modulus and thermal expansivity will be given. The theory opens the possibility of determining interfacial strengths from appropriate mechanical and thermal measurements and of predicting one set from another set of dat
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