Thermodynamics of the Y‐Ba‐Cu‐C‐O‐H System: Application to the Organometallic Chemical Vapor Deposition of the YBa2Cu3O7−xPhase
作者:
Constantin Vahlas,
Theodore M. Besmann,
期刊:
Journal of the American Ceramic Society
(WILEY Available online 1992)
卷期:
Volume 75,
issue 10
页码: 2679-2686
ISSN:0002-7820
年代: 1992
DOI:10.1111/j.1151-2916.1992.tb05488.x
出版商: Blackwell Publishing Ltd
数据来源: WILEY
摘要:
A calculational thermodynamic investigation of the chemical vapor deposition (CVD) of YBa2Cu3O7−xfrom organometallic precursors has been performed, based on the minimization of the Gibbs energy of the Y‐Ba‐Cu‐C‐O‐H chemical system. Thermodynamic data for the participating compounds were selected after a critical assessment of the available thermochemical information and are self‐consistent with an accepted phase diagram. The results are presented in CVD diagrams which illustrate the influence of the most commonly used operating conditions of temperature, pressure, and initial gas composition on the formation of
点击下载:
PDF
(848KB)
返 回