A COMPARISON OF SLATER'S THEORY OF UNIMOLECULAR REACTIONS WITH EXPERIMENTAL DATA
作者:
Everett Thiele,
David J. Wilson,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1959)
卷期:
Volume 37,
issue 6
页码: 1035-1037
ISSN:0008-4042
年代: 1959
DOI:10.1139/v59-148
出版商: NRC Research Press
数据来源: NRC
摘要:
Slater's theory of unimolecular reactions is tested by comparing theoretical and experimental values of the pressure at which the rate constant has fallen off from the high-pressure limit by 5%. A simplified method is used for calculating lower bounds to the theoretical value of this pressure. Agreement with experimental data on cyclobutane, cyclobutene, and nitrogen pentoxide is rather poor; experimental values are lower than the calculated lower bounds.
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