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Kinetics of methane hydrate formation in aqueous electrolyte solutions

 

作者: P.D. Dholabhai,   N. Kalogerakis,   P.R. Bishnoi,  

 

期刊: The Canadian Journal of Chemical Engineering  (WILEY Available online 1993)
卷期: Volume 71, issue 1  

页码: 68-74

 

ISSN:0008-4034

 

年代: 1993

 

DOI:10.1002/cjce.5450710110

 

出版商: Wiley Subscription Services, Inc., A Wiley Company

 

关键词: kinetics;methane;hydrates;crystallisation;electrolytes

 

数据来源: WILEY

 

摘要:

AbstractExperimental data on the kinetics of methane hydrate formation in aqueous electrolyte solutions are reported. The experiments were carried out in a semi‐batch stirred tank reactor in three NaCl and two KCl solutions as well as in a solution containing a mixture of NaCl and KCl at three different nominal temperatures from 270 to 274 K and at pressures ranging from 3.78 to 7.08 MPa. The kinetic model developed by Englezos et al. (1987a) was adapted to predict the growth of hydrates. The model is based on the crystallisation theory coupled with the two‐film theory for gas absorption in the liquid phase. The kinetic rate constant which appears in the model was that obtained earlier for methane hydrate formation in pure water. The effect of the electrolytes was taken into account through the computation of the three‐phase equilibrium conditions and the corresponding fugacities. Overall, the model predictions match the experimental data very well with the largest prediction error being less tha

 

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