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L-Glucose. A convenient synthesis fromD-glucose

 

作者: Walter A. Szarek,   George W. Hay,   Dolatrai M. Vyas,   Edward R. Ison,   Lucjan J. J. Hronowski,  

 

期刊: Canadian Journal of Chemistry  (NRC Available online 1984)
卷期: Volume 62, issue 4  

页码: 671-674

 

ISSN:0008-4042

 

年代: 1984

 

DOI:10.1139/v84-112

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

L-Glucose has been synthesized fromD-glucose by a convenient method involving methyl 2,3-O-isopropylidene-β-D-gulo-furanosiduronic acid (6) as a key intermediate. Compound6was converted intoL-glucono-1,5-lactone (8), which, by a selective reduction, affordedL-glucose (9).

 

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