Photometric Study of the Oxygen Diffusivity in an Aluminosilicate Glass
作者:
W. N. Lawless,
Brent Wedding,
期刊:
Journal of Applied Physics
(AIP Available online 1970)
卷期:
Volume 41,
issue 5
页码: 1926-1929
ISSN:0021-8979
年代: 1970
DOI:10.1063/1.1659143
出版商: AIP
数据来源: AIP
摘要:
The diffusivity of oxygen in an aluminosilicate glass from 630° to 830°C is derived from optical transmission measurements, wherein the rate of bleaching of Ti3+color centers by the diffusing oxygen at temperature was measured. The finite‐thickness solution to the heat equation is used to interpret the data; the oxygen diffusivity on this temperature range can be represented byD=28.4 exp (−39.6±3.4 kcal/RT)cm1/sec. It is concluded that the oxygen diffuses interstitially as molecular oxygen, because the activation energy is smaller than the energy to split an Si&sngbnd;O bond: 50 kcal/mole. As a check on the technique and results, penetration measurements were made on a moving color boundary, with identical results.
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