Flash pyrolysis nozzle for generation of radicals in a supersonic jet expansion
作者:
Daniel W. Kohn,
Horst Clauberg,
Peter Chen,
期刊:
Review of Scientific Instruments
(AIP Available online 1992)
卷期:
Volume 63,
issue 8
页码: 4003-4005
ISSN:0034-6748
年代: 1992
DOI:10.1063/1.1143254
出版商: AIP
数据来源: AIP
摘要:
A method for the high‐temperature generation of reactive species in supersonic molecular beams has been developed. Pyrolysis temperatures (25–1800 °C) can be maintained for longer than 100 h for extended experiments. Short contact time (≊10 &mgr;s) of the seeded (<1 Torr partial pressure in 2 atm inert carrier gas) precursor molecules suppresses recombination of the product radicals. Number densities for radicals are estimated to be ≊1014cm−3at the sonic orifice with radical fluxes of ≊1016s−1.
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