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Shear and time‐dependent rheology of a fully nematic thermotropic liquid crystalline copolymer

 

作者: Douglass S. Kalika,   David W. Giles,   Morton M. Denn,  

 

期刊: Journal of Rheology  (AIP Available online 1990)
卷期: Volume 34, issue 2  

页码: 139-154

 

ISSN:0148-6055

 

年代: 1990

 

DOI:10.1122/1.550116

 

出版商: The Society of Rheology

 

关键词: Liquid crystalline polymers;Nematic phase;Thermotropic phase;Rheological measurements;Torsional measurements;Thermal history effects;Crystalline annealing;LIQUID CRYSTALS;COPOLYMERS;PHTHALATES;POLYETHYLENES;SHEAR;RHEOLOGY;ANNEALING

 

数据来源: AIP

 

摘要:

Rheological measurements are reported for a fully nematic thermotropic liquid crystalline copolyester composed of 80%p‐hydroxybenzoic acid/20% poly(ethylene terephthalate). The polymer displays shear thinning behavior with a constant power‐law index over eight decades of shear rate; no shear‐independent plateau (region II) is observed. Dynamic time sweeps indicate a high sensitivity of the rheological parameters to thermal history, apparently resulting from crystalline annealing. These annealing effects could be erased by appropriate thermal cycling. Torsional measurements (cone‐and‐plate) were limited at high shear rates by the occurrence of edge fracture. This instability was typically accompanied by an unusual sample texture composed of concentric rings, which was particularly distinct when offgassing had occurred in the polymer melt.

 

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