Excluded‐volume effects in dilute polymer solutions. IV. Polyisobutylene
作者:
T. Matsumoto,
N. Nishioka,
H. Fujita,
期刊:
Journal of Polymer Science Part A‐2: Polymer Physics
(WILEY Available online 1972)
卷期:
Volume 10,
issue 1
页码: 23-42
ISSN:0449-2978
年代: 1972
DOI:10.1002/pol.1972.160100103
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractStatistical radii of gyration, second virial coefficients, and intrinsic viscosities of sharp fractions (M̄w/M̄n≈ 1.1) of polyisobutylene (PIB) covering a wide range of molecular weight (1.6 × 105to 4.7 × 106) were determined in isoamyl isovalerate (IAIV) at a number of temperatures ranging from 20 to 60°C, inn‐heptane at 25°C, and in cyclohexane at 25°C by light‐scattering and viscosity measurements. It was found that IAIV at 22.1°C is a theta solvent for PIB. Analysis of the data by the methods described in preceding papers of this series indicated that, except for minor differences, the conclusions derived from similar studies with polychloroprene, polystyrene, and poly‐p‐methylstyrene hold equally for solutions of the typical linear polymer investigated here. In particular, no decisive evidence for the drainage
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