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Use of Methyl 3- (N,N-Dimethylamino) Propionate as a Synthon for the Construction of α-Methylene γ-Butyrolactones

 

作者: Lin-Chen Yu,   Paul Helquist,  

 

期刊: Synthetic Communications  （Taylor Available online 1981）
卷期: Volume 11, issue 7  

页码: 591-597

 

ISSN:0039-7911

 

年代: 1981

 

DOI:10.1080/00397918108063629

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The lithium enolate of methyl 3-(N,N-dimethylamino) propionate reacts with allylic halides to give alkylation products which may be converted into α-methylene γ-butyrolactones by a reaction sequence which includes iodolactonization among other simple steps.

 

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