Transitions in semicrystalline polymers. I. poly(vinyl Fluoride) and poly(vinylidene fluoride)
作者:
JohnB. Enns,
Robert Simha,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1977)
卷期:
Volume 13,
issue 1
页码: 11-24
ISSN:0022-2348
年代: 1977
DOI:10.1080/00222347708208750
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The relaxation phenomena of two semicrystalline polymers, poly(vinyl fluoride) and poly(vinylidene fluoride) were studied by a dilaitometric technique in the temperature range from—30°C to 200°C. The premelting (Tαc), upper [Tg(U)] and lower glass [Tg(L)] transitions are observed for both polymers, as well as a transition in PVF2which is sensitive to thermal history. Comparison of our results with previous work, in most cases at higher frequencies, as well as thermal treatment of PVF2allow us to make assignments and calculate activation energies for the relaxations. Certain characteristic quantities are given, namely, T < Tg(L)/Tg(L), Tg(L)/Tm, and Tαc/Tm, as well as αΔgand ΔαTg.
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