1.The effect of the C6F5group on the ΝC=0 frequency of C6F5COR compounds depends on the structural features of the R fragment; for ketones, amides, and hydrazides there is steric inhibition of resonance in the C6F5CO group and an increase in the role of the inductive effect from C6F5.2.In N-dimethylpentafluorobenzamide the decrease in resonance is compensated by p,π-conjugation in the CON group, and the inductive effect of the C6F5ring appears to be weaker than in pentafluoroacetophenone.3.The presence of the second nitrogen atom and the change in relative orientation of the unshared electron pair when affected by substituents at N1and N2in pentafluorobenzahydrazide molecules leads to an increase in the torsion angle in C6F5-CO in comparison to N-dimethylpentafluorobenzamide, which increases the -I effect of C6F5on ΝC=0 in pentafluorobenzhydrazid