Synthesis and micellar behaviour of some novel amphiphilic acrylate and methacrylate monomers
作者:
Shakeeb M. Hamid,
David C. Sherrington,
期刊:
British Polymer Journal
(WILEY Available online 1984)
卷期:
Volume 16,
issue 1
页码: 39-45
ISSN:0007-1641
年代: 1984
DOI:10.1002/pi.4980160108
出版商: John Wiley&Sons, Ltd
关键词: Acrylic amphiphiles;monomer micellisation
数据来源: WILEY
摘要:
AbstractThe syntheses of a number of acrylate and methacrylate based amphiphiles are described. One group consists essentially of quaternary ammonium salts and the other of potassium carboxylates. Two non‐ionic species based on oligoethylene oxides are also described. The critical micelle concentration of each has been determined from conductance and dye absorption data, and the values compare satisfactorily with literature data on similar non‐polymerisable molecules. The compounds readily oligomerised in bulk, and in the micellar state the dye absorption data also indicated oligomerisation initiated by a free radical sou
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