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Retrograde Densification of Calcined and Glass Precursors of Approximate (Bi,Pb)2Sr2Ca2Cu3O10Stoichiometry

 

作者: Dimitri N. Argyriou,   Eric R. Vance,  

 

期刊: Journal of the American Ceramic Society  (WILEY Available online 1992)
卷期: Volume 75, issue 5  

页码: 1269-1271

 

ISSN:0002-7820

 

年代: 1992

 

DOI:10.1111/j.1151-2916.1992.tb05568.x

 

出版商: Blackwell Publishing Ltd

 

关键词: densification;superconductors;kinetics;glass;high temperature

 

数据来源: WILEY

 

摘要:

Retrograde densification of pelletized calcines and glasses having an approximate (Bi,Pb)2Sr2Ca2Cu3O10starting stoichiometry and sintered at ∼850°C can be described by first‐order rate equations. Retrograde densification in the calcine precursors was largely due to the development of open pores, and was approximately proportional to the concentration of the (Bi,Pb)2Sr2CaCu3O10phase. In the glasses, retrograde densification is mainly caused by porosity accompanying the growth of a needlelike Sr─Ca─Cu─O phase, together with (Bi,Pb)2Sr2Ca2Cu3O10and (Bi,Pb)2

 

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