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Synthesis of (±)- andMeso-Limatulone, Defensive Triterpene Metabolites of the LimpetCollisella Limatula

 

作者: Kenji Mori,   Hirosato Takikawa,   Masaru Kido,   K.F. Albizati,   D.John Faulkner,  

 

期刊: Natural Product Letters  （Taylor Available online 1992）
卷期: Volume 1, issue 1  

页码: 59-64

 

ISSN:1057-5634

 

年代: 1992

 

DOI:10.1080/10575639208048887

 

出版商: Taylor & Francis Group

 

关键词: Antifeedant;Collisella limatula;Defensive metabolite;Limatulone;synthesis of Limpet;Triterpene;X-ray analysis

 

数据来源: Taylor

 

摘要:

The limpetCollisella limatulawas found to produce both (±)- andmeso-limatulone (1aand1b) as defensive metabolites. Their structures were confirmed by a total synthesis coupled with X-ray crystallographic analysis of the intermediate,meso-13a.

 

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