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Solvent Effects on the Electronic Absorption Spectrum of CrC(NO3)36H2O

 

作者: Józef Myrczek,   Adam Bartecki,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1987）
卷期: Volume 20, issue 5  

页码: 431-438

 

ISSN:0038-7010

 

年代: 1987

 

DOI:10.1080/00387018708081563

 

出版商: Taylor & Francis Group

 

关键词: electronic absorption spectra;solvent effects;transition metal complexes;chromium (III) compounds;computer resolution of spectra

 

数据来源: Taylor

 

摘要:

Non-specific solvent effects on the electronic absorption spectra of Cr(N0336H20 in water, methanol, ethanol, t-butanol and in their binary mixtures were investigated. The spectra were carefully treated using a computer resolution technique. The high correlation between dielectric constant of solvents and the crystal field parameter Dq as well as between refractivity index and oscillator strength of the d-d bands were observed. A concept of a new spectrochemical series has been formulated.

 

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