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Novel Synthesis of Penta-N,O-Acetylvaliolamine

 

作者: Mitsuo Hayashida,   Nobuo Sakairi,   Hiroyoshi Kuzuhara,  

 

期刊: Journal of Carbohydrate Chemistry  （Taylor Available online 1988）
卷期: Volume 7, issue 1  

页码: 83-94

 

ISSN:0732-8303

 

年代: 1988

 

DOI:10.1080/07328308808058905

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Penta-N,O-acetylvaliolamine (11), a derivative of microbial α-D-glucosidase inhibitor, was prepared from the chiral azido-containing cyclohexene derivative derived fromD-glucose. Novel rearrangement of the C-C double bond accompanying reduction of the azido group vas a key step for the preparation.

 

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