Effects of branches and acetyl or acetal groups on stress-induced crystallization of poly(vinyl alcohol) from its aqueous solutions
作者:
S. Matsuzawa,
K. Yamaura,
S. Kinugasa,
M. Suzuki,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1974)
卷期:
Volume 9,
issue 1
页码: 1-17
ISSN:0022-2348
年代: 1974
DOI:10.1080/00222347408204537
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Atactic poly(vinyl alcohol) (PVA), which has some branches or acetyl groups, was crystallized by shearing force under turbulent flow from its aqueous solution in order to clarify the effects of branches or acetyl groups on the shearing stress-induced crystallization. The crystallization became more difficult with an increase in their number. In partially acetylated PVA, the acetyl groups of randomly acetylated PVA markedly influenced the shearing stress-induced crystallization in comparison with that of nonrandomly acetylated PVA. In addition, this paper describes the shearing: stress-induced crystallization under laminar flow of syndiotactic-rich PVA partially acetalized with glyoxylic acid.
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