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The Swelling of Unfilled and Highly Filled Polymers

 

作者: K. W. Bills,   F. S. Salcedo,  

 

期刊: Journal of Applied Physics  (AIP Available online 1961)
卷期: Volume 32, issue 11  

页码: 2364-2367

 

ISSN:0021-8979

 

年代: 1961

 

DOI:10.1063/1.1777075

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The swelling of elastomers in solvents is a useful method for determining the effective crosslinking of the polymeric structure. However, it is now shown that this method may be applied satisfactorily to highly filled polymers. A unique method has been devised for the accurate measurement of the swelling ratio of the gel phase of the filled polymers. The method is based on the observation that the binder‐filler bond, for most filler particles, releases on swelling. The binder around the particle swells, leaving a hollow pocket which becomes filled with solvent. Corrections for this ``waste'' solvent lead to the equations from which the swelling of the polymer can be calculated. Experimental verification is given for several filled systems.

 

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