Voltammetric and Coulometric Studies on Eugenol and Related Compounds
作者:
M. Iguchi,
A. Nishiyama,
Y. Terada,
S. Yamamura,
期刊:
Analytical Letters
(Taylor Available online 1979)
卷期:
Volume 12,
issue 10
页码: 1079-1087
ISSN:0003-2719
年代: 1979
DOI:10.1080/00032717908082535
出版商: Taylor & Francis Group
关键词: Anodic oxidation;Cyclic voltammetry;Potentiostatic/galvanostatic electrolysis;HPLC-monitoring;Phenols
数据来源: Taylor
摘要:
Anodic processes were studied for eugenol, isoeugenol and 2,6-dimethoxy-4-allylphenol by cyclic voltammetry at a glassy carbon electrode in methanol. Preparative electrolyses were also applied coulometrically to these phenols, followed by the separation and the determination of the structures of -e, -2e and -4e products. It was indicated that both radical and cationic reactions were controlled by the applied potentials, the solvent media and the substituents on the aromatic rings.
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