The Structures of Humulene Diepoxides Found in Hops and Beer
作者:
PeacockVal E.,
DeinzerMax L.,
期刊:
Journal of the American Society of Brewing Chemists
(Taylor Available online 1989)
卷期:
Volume 47,
issue 1
页码: 4-6
ISSN:0361-0470
年代: 1989
DOI:10.1094/ASBCJ-47-0004
出版商: Taylor&Francis
关键词: Humulene diepoxide;Humulene epoxide
数据来源: Taylor
摘要:
Three isomeric humulene epoxides (I–III) were oxidized withm-chloroperbenzoic acid to their corresponding diepoxides (A–E) to determine the positions of the epoxide rings of the five known diepoxides. Humulene epoxide I gives three diepoxides designated A, B, and C. Epoxide II gives diepoxides A, B, D, and E. Epoxide III gives C, D, and E. Therefore, diepoxides A and B have epoxide rings in the positions of the monoepoxides I and II, diepoxide C in positions I and III, and diepoxides D and E in positions II and III. X-ray analysis of purified humulene diepoxide A showed it to have the epoxide rings trans, therefore the rings of B must be cis.
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