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Infrared Circular Dichroism of Liquid Crystals

 

作者: N. Teramae,   K. Kuroda,   M. Hiroguchi,   S. Tanaka,  

 

期刊: Spectroscopy Letters  (Taylor Available online 1982)
卷期: Volume 15, issue 3  

页码: 175-186

 

ISSN:0038-7010

 

年代: 1982

 

DOI:10.1080/00387018208062660

 

出版商: Taylor & Francis Group

 

关键词: Circular Dichroism;Optical Activity;FTIR;Fourier Transform;Infrared;Liquid Crystal

 

数据来源: Taylor

 

摘要:

A measurement system for infrared circular dichroism (IRCD) was constructed by using a home-made CD measuring attachment and a Fourier transform infrared spectrometer, and some tentative evaluations of its performances were made. IRCD spectra were measured for nematic liquid crystals such as 4-cyano-4-n-pentyl biphenyl (K-15) which exhibited optical activity caused by the effect of surface-induced orientation and/or by doping with a small amount of chiral guest molecules, and these spectra were compared with each other. It was found that the IRCD spectra of K-15 without chiral guest molecules showed opposite signs depending on the configurations of the two rubbed windows on which polyimide was coated. IRCD spectra of K-15 could be also measured without chiral guest molecules and rubbing procedures, when two NaCl windows were coated with poly-γ-methyl-L-glutamate.

 

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